Technical Alerts - September 2021

Technical News,

TechAlerts

Abstracts that tickle this reviewer's interest

Courtesy of Google Scholar

 

Year - Month: 2021-09

 

[PDF]Changes in Latina Women's Exposure to Cleaning Chemicals Associated with Switching from Conventional to “Green” Household Cleaning Products: The LUCIR …

KG Harley, L Calderon, JES Nolan, R Maddalena… - Environmental Health …, 2021

… 35.5 % ). We observed significant increases in air concentrations of three fragrance
compounds: the plant-derived terpene, beta-myrcene (221.5%), and the synthetic
musks celestolide (31.0%) and galaxolide (79.6%). Almost …

Of value in understanding the future of the pine oil market. Hint: not good!

 

[HTML]Phytosterols and Cardiovascular Disease

U Makhmudova, PC Schulze, D Lütjohann… - Current Atherosclerosis …, 2021

… Plant Sterol Biochemistry and Physiology … As a result of this selection, which can be
interpreted as a “defense mechanism” against phytosterols, plasma plant sterol
concentration is 1000-fold lower than plasma cholesterol levels. Fig. 1 figure1 …

 

[PDF]Cholesterol-to-Coprostanol Conversion by the Gut Microbiota: What We Know, Suspect, and Ignore

C Juste, P Gérard - Microorganisms, 2021

… bacteria. Cholesterol is mainly converted into coprostanol, a non-absorbable sterol
that is excreted in the feces … bacteria. Cholesterol is mainly converted into coprostanol,
a non-absorbable sterol that is excreted in the feces …

Fascinating review of one of the main ways cholesterol is removed from the body

 

Influence of the rosin side-chain groups on the solution properties of a high molecular weight hydrogenated poly (norbornene)

N Hamidi, MS Ganewatta - Polymer, 2021

… resin acids, which have a tertiary carboxylic acid group, unsaturations, and
a bulky hydrophenanthrene ring structure that can increase glass transition
temperature and render hydrophobicity to any substrates to which it is attached …

 

CatalyticTerpenePolycyclization Reactions and Structural Determination of Small Molecules by MicroED

JE Burch - 2021

This dissertation describes the development of Lewis acid-based methodology to
access polycyclized sesquiterpenes and diterpenes through simple catalytic
methods. This challenging biomimetic reaction is difficult to replicate in synthesis and …

 

[PDF] Controlling Stored Products' Pests with Plant Secondary Metabolites: A Review

P Nikolaou, P Marciniak, Z Adamski, N Ntalli - Agriculture, 2021

Page 1. agriculture Review Controlling Stored Products' Pests with Plant Secondary
Metabolites: A Review Polyxeni Nikolaou 1, Paweł Marciniak 1 , Zbigniew Adamski
1,2 and Nikoletta Ntalli 3,* Citation: Nikolaou, P.; Marciniak …

 

Effects of α-Pinene Sulfur Dioxide-Free Red Winemaking

侯政廷 - 2021

… were analyzed. α-pinene is a perfume monomer compound derived from fruit aroma
substances including grapes, and is one of theterpenefamilies, and has physiological
activities such as antibacterial and antioxidation. The …

Well, who would have guessed that our favorite terpene is good for our favorite beverage!

 

Burners for Liquid Fuels

V Raghavan - Combustion Technology, 2022

As mentioned in earlier chapters, liquid fuels are either vaporized or
atomized into droplets before they are injected into a combustion chamber.
The vaporization and atomization characteristics of...

Since tall oil derivatives are used in fuel mixtures, a basic understanding of this subject may be valuable.

 

 

Limonene: formulation and insecticide use
United States Patent 11109587 B2 · Filed: 10/20/2015 · Published: 09/07/2021

 

11109587

Limonene: formulation and insecticide use
The current invention concerns a composition, in the form of an emulsifiable concentrate, comprising more than 50% limonene as active ingredient and a surfactant system with an anionic wetting...

Assignee:

AGRYPHAR SPRL (Seraing, BE)

Inventors:

Pirotte, Alan (Houffalize, BE)

The current invention concerns a composition, in the form of an emulsifiable concentrate, comprising more than 50% limonene as active ingredient and a surfactant system with an anionic wetting agent and a non-ionic polymeric surfactant and with less than 10 wt % solvent. The composition with high load of nature derived active ingredient remains stable, preferably even when subjected to cold storage. The invention also provides in the use of a limonene comprising composition as acaricide or insecticide, and in a method of treating plants and crops with a limonene comprising composition.

A green active/insecticide??

 

Process for the preparation of alpha, beta unsaturated aldehydes by oxidation of alcohols in the presence of a liquid phase
United States Patent 11111197 B2 · Filed: 12/05/2018 · Published: 09/07/2021

Process for the preparation of alpha, beta unsaturated aldehydes by oxidation of alcohols in the presence of a liquid phase.

This patent shows BASF is still committed to research to bolster its position in synthetic flavors and fragrances, and vitamins.  This is all geared to its citral-nerol-geraniol-ionones product line.  BASF is still working on l-menthol from isobutylene which utilizes some of the same type conversions.

 

Pneumatic tire
United States Patent 11118036 B2 · Filed: 11/02/2016 · Published: 09/14/2021

Assignee:

THE GOODYEAR TIRE & RUBBER COMPANY (Akron, OH, US)

Inventors:

Isitman, Nihat Ali (Ettelbruck, LU)
Pompei, Manuela (Reuler, LU)
Engeldinger, Eric (Attert, LU)

This patent invention takes advantage of a somewhat unexpected finding that low Tg hydrocarbon and terpene resins can provide better wet skid resistance without sacrificing tread wear.

Light color rosin ester compositions and methods of making same
United States Patent 11111411 B2 · Filed: 04/01/2020 · Published: 09/07/2021

Assignee:

KRATON POLYMERS LLC (Houston, TX, US)

Inventors:

Schaapman, Mark (Almere, NL)

This patent describes a combination of chemistries to produce 100 degC softenting PE rosin esters, one of which is the employ of xanthone and related compounds and the employ of dienophiles like maleic acid.  Colors roughly 2-2.5 down to <1 are possible.

METHODS OF KILLING NEMATODES COMPRISING THE APPLICATION OF A TERPENE  COMPONENT
European Patent EP1711058 B1 · Filed: 01/24/2005 · Published: 09/15/2021

Assignee:

EDEN RESEARCH PLC (Abingdon Oxfordshire OX14 4RQ, GB)

Inventors:

FRANKLIN LANNY (US)
OSTROFF GARY (US)

 

This invention is aimed at eradicating nematodes with readily available terpenes such as alpha-terpineol and citral.  More green pesticides.

ADJUVANT COMPOSITIONS
European Patent EP2811828 B1 · Filed: 01/18/2013 · Published: 09/01/2021

Assignee:

SYNGENTA PARTICIPATIONS AG (4058 Basel, CH)
SYNGENTA LTD (Bracknell, Berkshire RG42 6EY, GB)

Inventors:

STOCK DAVID (GB)
TAYLOR PHILIP (GB)
RAMSAY JULIA LYNNE (GB)
BELL GORDON ALASTAIR (GB)
ASHFORD EMMA JANE (CH)

 

The present invention relates generally to adjuvants for agrochemicals. In particular, the present invention relates to the use of certain terpenic  alkoxylates as adjuvants to improve the performance of agrochemicals and to agrochemical compositions containing such adjuvants.

The present invention provides mixtures comprising certain terpenic  alkoxylate adjuvants A and an agrochemical component B. Component B is an agrochemical active ingredient. Suitable agrochemical active ingredients include insecticides, acaricides, nematocides, molluscicides, fungicides, herbicides, plant growth regulators as well as fertilizers and micronutrients.

It has now been found, surprisingly, that the agrochemical active ingredient - adjuvant mixture according to the invention can extend the range of action of the agrochemical active ingredient e.g. by achieving a synergistic effect. Thus, the rates of application of the components are lowered whilst the action remains equally good. Secondly, the active ingredient mixture still achieves a high degree of pest or weed control, sometimes even where the two individual components have become totally ineffective in such a low application rate range. This allows increased safety in use or any other advantages familiar to a person skilled in the art.

TALL OIL DERIVED GLYCIDYL ESTERS AND PROCESS OF MAKING THE SAME
WIPO Patent Application WO/2021/188613 A1 · Filed: 03/17/2021 · Published: 09/23/2021

Assignee:

INGEVITY SOUTH CAROLINA LLC (US)

Inventors:

WANG BING (US)
GANEWATTA MITRA (US)

Renewable thermosetting polymers??

 

Courtesy of Kerry Thompson, Nelson Lawson, and the PCA.